One-step-impregnation hard templating synthesis of high-surface-area nanostructured mixed metal oxides (NiFe2O4, CuFe2O4 and Cu/CeO2).
نویسندگان
چکیده
We report here on an efficient one-step-impregnation method to synthesize crystalline mesoporous bimetal oxides (e.g. NiFe(2)O(4), CuFe(2)O(4), Cu/CeO(2)) using mesoporous silicas as hard templates under optimized mixing conditions. This new procedure enables a true replication of the mesostructure with high yield and phase purity, while retaining particle morphology of the template.
منابع مشابه
Study of CO Oxidation Activity and Chemical Characterisation of Cu/CeO2 Powder
The catalytic activity for CO oxidation over cerium dioxide (CeO2) and Cu-modified ceria (Cu/CeO2) powders prepared by wetness impregnation method was investigated in flow tube reactor system under atmospheric pressure. Reaction curves of powder samples pre-treated by calcination in mixture of argon and oxygen and by reduction in hydrogen, all at 300 °C were measured. X-ray photoelectron spectr...
متن کاملSteam Reforming of Bio-Ethanol to Produce Hydrogen over Co/CeO2 Catalysts Derived from Ce1-xCoxO2-y Precursors
A series of Ce1 ́xCoxO2 ́y precursors were prepared by homogeneous precipitation using urea as a precipitant. The Co/CeO2 catalysts obtained from the Ce1 ́xCoxO2 ́y precursors were used for the steam reforming of ethanol to produce hydrogen. Co ions could enter the CeO2 lattices to form Ce1 ́xCoxO2 ́y mixed oxides at x ď 0.2 using the homogeneous precipitation (hp) method. CeO2 was an excellent suppo...
متن کاملNanofabrication of highly ordered, tunable metallic mesostructures via quasi-hard-templating of lyotropic liquid crystals
The synthesis of metal frameworks perforated with nanotunnels is a challenge because metals have high surface energies that favor low surface area structures; traditional liquid-crystal templating techniques cannot achieve the synthetic control required. We report a synthetic strategy to fabricate metal nanomaterials with highly ordered, tunable mesostructures in confined systems based on a new...
متن کاملRigid templating of high surface-area, mesoporous, nanocrystalline rutile using a polyether block amide copolymer template.
Highly crystalline rutile with a specific surface area as high as 280 m(2) g(-1) and well-connected uniform mesoporosity has been synthesized by rigid templating using commercial, low-cost polyether block amide. This general, simple synthesis route for high surface-area mesoporous nanocrystalline oxides and nanocomposite membranes is important for catalysis, sensors, energy storage, solar cells...
متن کاملCatalytic Decomposition of Hydrocarbon Gas over Various Nanostructured Metal oxides for Hydrocarbon Removal and Production of Carbon Nanotubes
Nanosized CuO-CeO2, CuO-Fe2O3, CuO-CeO2-Al2O3 and CuO-Fe2O3-CeO2-Al2O3 were prepared by co-precipitation and wet impregnation techniques and were used for Catalytic decomposition of acetylene to produce carbon nanotubes (CNTs). Weight gain technique was used to follow up the catalytic reactions. The results revealed that catalyst chemical composition, catalytic temperature, acetylene flow rate ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 47 37 شماره
صفحات -
تاریخ انتشار 2011